It typically occurs in alloys, such as stainless steel, and not in pure metals. Webcorr provides corrosion consultancy services, corrosion expert witness and corrosion short courses for inhouse training, online and distance learning. From the chemical composition point of view, corrosion resistant nickel based alloys are categorized as pure nickel, nickelcopper alloys, nickelmolybdenum alloys, nicrmo alloys and nicrfemo alloys. This article describes the susceptibility of 316l stainless steel to stress corrosion cracking scc in a nitritecontaining chloride solution. Selection of metallic materials for stress corrosion cracking resistance in sodium chloride environments 1. The required tensile stresses may be in the form of directly applied stresses or in the form of residual. Chloride stress corrosion cracking inspectioneering. Stress corrosion cracking of austenitic type 304 stainless. Stress corrosion cracking of brass in ammonia solutions was carried out with guidelines given by astm standard g3798. Stress corrosion cracking can be either intergranular along the grain boundaries, figure 1, or transgranular across the grains, figure 2, or both, depending on the conditions. This type of failure is known as stress corrosion cracking, often abbreviated to scc. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. Transgranular stress corrosion cracking occurs mainly in chloride cracking of austenitic steels.
The most common type of stress corrosion cracking in stainless steels occurs in chloride environments, which will be the focus of this discussion. This excludes corrosion reduced sections that fail by fast fracture. Soilside chlorideinduced stress corrosion cracking under. Stress corrosion cracking scc is a common issue with many specialty alloys. Transgranular attack has a very characteristic branching habit which is easily recognizable in scanning electron microscopy sem fractographic and metallographic section examination. It also excludes intercrystalline or transcrystalline corrosion, which can disintegrate an alloy without applied or residual stress. After deep inspection, the flange was found to have stress corrosion cracking scc caused by the unknown presence of chloride in the system. Pdf localized corrosion and stress corrosion cracking of stainless. The stress corrosion cracking scc behavior of aisi347 austenitic stainless. This test is performed to determine the degree of stress corrosion cracking of brass under one or more specific stress.
In order for scc to occur there must be a corrosive environment, a susceptible material, and a driving force. When a chemically susceptible material is exposed to a hostile environment. Stress corrosion cracking implies cracking due to combined effect of corrosion with stress. The corrosion also tends to occur in an environment where stress is applied to the components. What is stresscorrosion cracking and why does it occur. Stress corrosion cracking scc is a sudden and difficulttopredict severe degradation mode. Addition of nitrite to the chloride solution, which is reported to have inhibitive influence on corrosion of stainless.
Stresses can occur for a variety of reasons, including welding, physical damage, forming, machining, grinding, heat treatment, and operating stresses. The combined action of tensile stress with corrosive environment can lead to chloride stress corrosion cracking cscc. The environmental factors that increase the cracking susceptibility include higher temperatures, increased chloride content, lower ph, and higher levels of tensile stress. Chloride stress corrosion involves selective attack of a metal along its grain boundaries. It can be detrimental to austenitic stainless steels, one of the main reasons these steels are not considered a cureall for corrosion problems. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. This document defines the design criteria that shall be used for the selection of metallic materials in order to prevent failure due to stress corrosion cracking. Stress corrosion cracking of an austenitic stainless steel in nitritecontaining chloride solutions r. Stress corrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. A508 cl 2 steel has been found to undergo stress corrosion cracking scc in pure water containing 1 or 8 ppm of oxygen at temperatures ranging from 100 to 288 c, as determined using constant extension rate tests certs. Metallographymicrostructure evaluation metallurgical. One of the most important forms of stress corrosion cracking can be stress corrosion cracking deriving from chloride, which it can be assumed as a type of intergranular corrosion.
Chloride stress corrosion cracks were also found at the corrosion sites. Susceptibility to stress corrosion cracking of 254smo ss. Incoloy 800 is used in the chemical plants for components of heat exchangers and transmission pipes of nitric acid solutions that need to prevent attack of chloride stress corrosion cracking. Corrosion and scc issues in watercooled nuclear power plants have been extensive, with intergranular stress corrosion cracking igscc and irradiationassisted stress corrosion iascc observed in numerous nickel and ironbased piping and heat exchanger materials 147161. This was routed back to the use of an antiseize grease used in the installation and maintenance procedure for the flange. Singh raman 1, and wai hoong siew 2 1 department of mechanical and aerospace engineering, monash university, melbourne, victoria 3800, australia 2 mechanical engineer, ibm australia 60 city road melbourne, victoria 3006 australia.
Uncertainty quantification methodologies development for. Stresscorrosioncracking view from the penthouse the. Stress corrosion cracking scc 1 is a common and dangerous form of cracking that occurs due to the combination of stress and corrosive environments. Effect of chloride deposition on stress corrosion cracking of 316l stainless steel used for intermediate level radioactive waste containers. Chloride stress corrosion cracking cl scc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Stress corrosion cracking scc is the progressive cracking of metals and alloys caused by the combined effect of sccprone microstructure. The investigation included visual examination, optical microscopy, scanning electron microscopy sem, energy dispersive spectroscopy eds, spectrometry, and metallography. The stress corrosion cracking of screws is a phenomenon where corrosion resistant materials, such as stainless steel, become cracked and damaged.
The article explains the scc, which occurs due to welding, metalworking process, and. Chloride is the leading cause of transgranular cracking. Stress corrosion cracking scc stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Scc is known as an insidious form of corrosion failure and it results in a significant drop in the. It has been reported that the environmentalfracture is discontinuous at the micron scale 4. In this report, the literature on stress corrosion cracking scc of the candidate. Analytical results revealed that crack was propagated at the outer surface of the welded zone. Synergistic effect of ac and cl on stress corrosion cracking. Stress corrosion cracking international institute of. This article commences with a discussion on the characteristics of stress corrosion cracking scc and describes crack initiation and propagation during scc. Stress corrosion cracking susceptibility of 304l substrate. Scc is often associated with chlorides, but can also occur with caustics and other corrosive media. Thierry, lowtemperature stress corrosion cracking of stainless steels in the atmosphere in the presence of chloride deposits, corrosion 65. Stress corrosion cracking of astm a508 cl 2 steel in.
Summary of available data for estimating chlorideinduced scc. After the ssrt, the scanning electron microscope sem is used to examine the. Influence of high temperature on corrosion behavior of 304. Cl and s elements were detected in corrosion products from the corrosion pits and the cracks by eds. Sensitized austenitic stainless steel suffers stress corrosion cracking. Stress corrosion cracking scc is cracking due to a process involving conjoint corrosion and straining of a metal due to residual or applied stresses.
The use of 316l would be more resistant to crevice corrosion attack. It is concluded that stress corrosion cracking was the main reason for the cracking of the elbow. Stress corrosion cracking behavior of nickel base alloys. This form of corrosion is controlled by maintaining low chloride ion and oxygen. Pdf chloride induced stress corrosion cracking of type 304 and. This study is to identify factors responsible for loss of production due to problems in plant and equipment. Chloride induced stress corrosion cracking of type 304 and. Stress corrosion cracking of an austenitic stainless steel. Soilside chloride induced stress corrosion cracking under insulation a length of tp 304 stainless steel pipe in service as a high pressure steam condensate return in an outdoor underground environment beneath a sidewalk along a roadway suffered cracking near its welded ends, while the main body showed no visual signs of failure.
Avoiding rtj flange stress corrosion cracking using. Chloride oxygen stress corrosion cracking mechanisms of austenitic chromiumnickel steels in high purity water at 250 to 350 c over a wide range of stress levels is reported. Stress corrosion cracking scc or called as environmentally assisted cracking eac may take place at the electrochemical potential range. External chloride stress corrosion cracking ecscc of insulated austenitic stainless steels e. Chloride cracking of austenitic stainless steels 300 series ss is an offshoot of cui, and theres nothing really magical about it.
Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. The metallurgical influences on the stress corrosion resistance of many commercial stainless steels have been studied using the fracture mechanics approach. Otherwise, through a scanning electron microscope sem fractograph, the. If you have insulated solid stainless steel equipment operating in the cui temperature range you are likely to eventually experience external chloride stress corrosion cracking ecscc. Materials free fulltext stress corrosion cracking of.
Dealloying has long been deemed unlikely in clscc of austenitic stainless steel. Chloride stress corrosion cracking scc of type 304 and 304l austenitic stainless steels ss was studied by a constant load method in air at a temperature of 353 k. Transgranular stress corrosion cracking tgscc is a typical fracture mode for the scc system of stainless steels in chloride environments, characterized by riverlike fractographs 15. Standard practice for use of mattssons solution of ph 7. Intergranular stress corrosion cracking an overview. A literature survey has been performed to identify scc crack growth rate cgr studies conducted. Also, the tip of crack contains some corrosion products according to the sem image fig. Stress corrosion cracking scc is cracking due to a process involving. Sensor requirements for detection and characterization of. Chloride induced stress corrosion cracking scc of austenitic stainless steel is a potential issue in long term dry storage of spent nuclear fuel canisters. Failure analysis of corrosion on stainless steel fasteners. Corrosion under insulation cui is a severe problem for 304 stainless steel pressure vessel. Chloride stress corrosion cracking cl scc is one of the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries.
Stress corrosion cracking of a 304 stainless steel elbow. The use of a duplex stainless steel with molybdenum such as stainless alloys 2205 or 2507 would resist crevice corrosion and stress corrosion cracking. Chloride stress corrosion cracking in austenitic stainless steel is characterized by the multibranched lightning bolt transgranular crack pattern. Observations of corrosion product formation and stress. When stainless steels are fully immersed, it is rare to see chloride stress corrosion cracking at temperatures below 60 c 150 f. Chlorideinduced transgranular stress corrosion cracking. Sem image of intergranular voids in the high strength low alloy steel.
The straightchromium ferritic stainless steels, twophase ferriticaustenitic stainless. Stresscorrosion cracking scc is a cracking process that requires the simultaneous action of a corrodent and sustained tensile stress. Stress corrosion cracking scc caused by atmospheric deposition and deliquescence of aggressive compounds such as chloride containing salts or oxidized sulfur species may pose a potential issue to the extended service life of spent nuclear fuel snf storage canisters. It failed by stress corrosion cracking, which was originated at the welded zone. The nucleation of stress corrosion cracks was connected with the formation of the film and the buildup of a high local concentration of cl observation by scanning electron microscopy and transmission electron microscopy showed the propagation of stress corrosion cracks was associated with selective corrosion of deformationinduced martensite. In the power production plants, the alloy is used in superheater and re. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Scc stress corrosion cracking cl chloride ions h 2 s hydrogen sulphide h 2 so 4 sulphuric acid nacl sodium chloride sem scanning electron microscope aisi american iron and steel institute astm american society for testing and materials nano 2 sodium nitrite na 2 so 4 sodium sulfate caoh 2 sodium hydroxide cr 23 c 6 chromium carbide. Pdf stress corrosion cracking of stainless steels in. There is a synergistic relationship between dissolved oxygen and the chloride level. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. Deterioration by cl scc can lead to failures that have the potential to release stored energy andor hazardous substances.
Representative sem image of a thumbnail crack found in a 316l sample. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. The influence of salt concentration, ph values and the addition of thiosulfate was examined. Pdf chloride stress corrosion cracking scc of type 304 and. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material.
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